About the Data Compilations
Compilation of data has emphasized the collection and review of reaction rate and associated property data for transient radicals, radical ions, and excited states in solution. These data largely result from the techniques of pulse radiolysis and flash photolysis and related methods which have produced a large body of information on short-lived transients.
Searchable Data
A searchable kinetics data base is currently available on the NIST website.
Data to Browse
Neta, P., J. Grodkowski, and A.B. Ross. "Rate Constants for Reactions of Aliphatic Carbon-Centered Radicals in Aqueous Solution." Journal of Physical and Chemical Reference Data 25 (1996): 709-1050. PDF (49 MB)
Buxton, G.P., Q.G. Mulazzani, A.B. Ross. "Critical Review of Rate Constants for Reactions of Transients from Metal-Ions and Metal-Complexes in Aqueous Solution." Journal of Physical and Chemical Reference Data 24 (1995): 1055-349. PDF (47.9 MB)
Wilkinson, F., W.P. Helman, A.B. Ross. "Rate Constants for the Decay and Reactions of the Lowest Electronically Excited Singlet State of Molecular Oxygen in Solution. An Expanded and Revised Compilation." Journal of Physical and Chemical Reference Data 24 (1995): 113-262. PDF (61.9 MB)
Wilkinson, F., W.P. Helman, A.B. Ross. "Quantum Yields for the Photosensitized Formation of the Lowest Electronically Excited Singlet State of Molecular Oxygen in Solution." Journal of Physical and Chmeical Reference Data 22 (1993): 113-262. PDF (29.1 MB)
Neta, P., R.E. Huie, A.B. Ross. "Rate Constants for Reactions of Peroxyl Radicals in Fluid Solutions." Journal of Physical and Chemical Reference Data (19) 1990: 413-513. PDF (16.1 MB)
Wardman, P. "Reduction Potentials of One-Electron Couples Involving Free Radicals in Aqueous Solution." Journal of Physical and Chemical Reference Data 18 (1989): 1637-755.. PDF (17.9 MB)
Hoffman, M.Z., F. Bolletta, L. Moggi, G.L. Hug. "Rate Constants for the Quenching of Excited States of Metal Complexes in Fluid Solution." Journal of Physical and Chemical Reference Data 18 (1989): 219-544. PDF (53.3 MB)
Neta, P., R.E. Huie, A.B. Ross. "Rate Constants for Reactions of Inorganic Radicals in Aqueous Solutions." Journal of Physical and Chemical Reference Data 17 (1988): 1027-284. PDF (41.2 MB)
Buxton, G.V., C.L. Greenstock, W.P. Helman, A.B. Ross. "Critical Review of Rate Constants for Reactions of Hydrated Electrons, Hydrogen Atoms and Hydroxyl Radicals (•OH/•O-) in Aqueous Solution." Journal of Physical and Chemical Reference Data 17 (1988): 513-886. PDF (66 MB)
Carmichael, I. G.L. Hug. "Triplet-Triplet Absorption Spectra of Organic Molecules in Condensed Phases." Journal of Physical and Chemical Reference Data 15 (1986): 1-250. PDF (44.2 MB)
Gordon, S., J.C. Sullivan, A.B. Ross. "Rate Constants for Reactions of Radiation-Produced Transients on Aqueous Solutions of Actinides." Journal of Physical and Chemical Reference Data (15) 1986: 1357-67. PDF (1,879 KB)
Bielski, B.H.J., D.E. Cabelli, R.L. Arudi, A.B. Ross. "Reactivity of HO2/O¯2 Radicals in Aqueous Solution." Journal of Physical and Chemical Reference Data 14 (1985): 1041-100. PDF (11.2 MB)