Jay A. LaVerne

Jay A. LaVerne

Lamar University, B.S. (1972)
University of Nebraska, Ph.D. (1981)

Phone: (574)631-5563
Email: laverne.1@nd.edu
Office: 316 Radiation Research Building

Radiation Chemical Effects with Heavy Ions


laverne

Scientific Interests

Experimental Heavy Ion Studies

Determination of product yields in the radiolysis of water, aqueous solutions, liquid hydrocarbons, polymers, resins, and ionic liquids with particles ranging from protons to uranium ions.

Condensed Phase Radiolysis

Examination of the main pathways for medium decomposition due to the passage of ionizing radiation.

Track Chemistry

Diffusion-kinetic modeling of the nonhomogeneous spatial distributions of the transient species produced by the absorption of energy by ionizing radiation.

Interfaces

Elucidation of the radiation chemical effects occurring at the interface of nanoparticles and water including condensed ices.

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Recent Accomplishments

Radiolysis of Ceramic Oxide- Water Interfaces

Modifications to water- nanoparticle interfaces induced by fast electron and g-irradiation- have been examined using Diffused Reflection Infrared Fourier Transform (DRIFT), Raman scattering, and electron paramagnetic resonance (EPR) techniques. Gas evolution studies show the transport of energy and charge through the interface is responsible for much of the observed radiation chemistry. These studies have identified the water layers near to, but not at, the interface for being the most radiation chemically active. Further studies are examining radiation effects following modification of the surfaces of a variety of ceramic oxides, including the iron oxides. Alpha particle radiolysis is being compared with the results found with conventional radiolysis.

Degradation of Polymers and Resins

The radiolysis of resins and polymers used in the separation and storage of waste materials have received considerable interest because of their applications in the nuclear industry. Polymers such as PVC clearly show substantial post irradiation effects due to the decays of long lived radicals, which can lead to formation of the corrosive chloride anion. PVC is extensively used in waste storage following the Fukushima accident and long term radiation effects are of vital importance. The radiolytic decay of resins such Reillex and Amberlite are very dependent on the amount of water present and various characteristics of the radiation. The production of H2 from these compounds is of considerable concern, and the degradation of medium decay products seems to be of great importance.

Hydrogen Peroxide Formation and Decomposition in Water

Hydrogen peroxide is one of the most important oxidizing species produced in the radiolysis of water with respect to radiation induced corrosion and yet the mechanism is only now becoming unraveled. Experiments have shown the H2Oreadily decays by first absorbing on the surface of ceramic oxides with the production of OH radicals. The presence of added H2 or variation in pH can affect the overall rate of H2O2 decomposition by methods not yet understood. Efforts are currently underway to map the radiolytic response to a variety of ceramic oxides for both fundamental information and for applications in waste storage.

State Selected Decomposition of Liquid Aromatics

The radiolytic response of several aromatic compounds are being examined with respect to the contributions made by high energy excited states. Molecular hydrogen production from the radiolysis of simple aromatic liquids with gamma rays is extremely low and these componds are typically thought to be radiation inert. However, the yield of H2 can increase dramatically with increasing linear energy transfer, LET, of the incident radiation. This increase was observed to be almost an order of magnitude from gamma rays to 5 MeV alpha particles. Simple heterogeneous substitutions or the addition of side chains has little effect on H2 yields. Most important, the yield of H2 was found to be independent of the phase so the simple liquid aromatic compounds can be used to infer radiolytic effects of solid compounds, which are by nature more difficult to examine.

Radiolysis of Ices at Interfaces

Radiation chemistry studies of simple alcohol ices condensed on aluminum have been performed using a newly developed ice chamber based on material science techniques. Molecular hydrogen formation from froze methanol, ethanol, and isopropanol is slightly lower at 77K than at room temperature, presumably because of gaminate recombination. Thin, nanometer, thick layers of alcohols were deposited and irradiated with electrons of 1 keV at 77K in the ice chamber. FTIR examination of these ices shows that conversion of the OH entity to an aldehyde in each of the ices. These studies are currently being extended to include condensed ices of simple amides.

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Selected Publications

Reiff, S.C., and J.A. LaVerne. "Radiation-Induced Chemical Changes to Iron Oxides." Journal of Physical Chemistry B (2015) link

Reiff, S.C. and J.A. LaVerne. "Gamma and He Ion Radiolysis of Copper Oxides." Journal of Physical Chemistry C 119 (2015): 8821-8828. link

Leay, L., W. Bower, G. Horne, P. Wady, A. Baidak, M. Pottinger, M. Nancekievill, A.D. Smith, S. Watson, P.R. Green, B. Lennox, J.A. LaVerne, and S.M. Pimblott. "Development of Irradiation Capabilities to Address the Challenges of the Nuclear Industry." Nuclear Instruments & Methods in Physics Research Section B: Beam Interactions with Materials and Atoms 343 (2014): 62-69. link

Mincher, B.J., S.P. Mezyk, G. Elias, G.S. Groenewold, J.A. LaVerne, A.R. Nilsson, J. Pearson, N.C. Schmitt, R.D. Tillotson, and L.G. Olsen. "The Radiation Chemistry of CMPO: Part 2. Alpha Radiolysis." Solvent Extraction and Ion Exchange 32 (2014): 167-178. link

Dhiman, S.B., G.S. Groff, W. Runde, and J.A. LaVerne. "Gamma and Heavy Ion Radiolysis of Ionic Liquids: A Comparative Study." Journal of Nuclear Materials 453 (2014): 182-187. link

Brown, A.R., P.L. Wincott, J.A. LaVerne, J.S. Small, D.J. Vaughan, S.M. Pimblott and J.R. Lloyd. "The Impact of g Radiation on the Bioavailability of Fe(III) Minerals for Microbal Respiration." Environmental Science and Technology 48 (2014): 10672-10680. link

 

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